Membrane Water Treatment Volume 8, Number 6, November 2017 , pages 563-574 DOI: https://doi.org/10.12989/mwt.2017.8.6.563 |
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Novel high performanced and fouling resistant PSf/ZnO membranes for water treatme |
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Adem Sarihan and Erdal Eren
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Abstract | ||
Antibacterial effective, high performanced, novel ZnO embedded composite membranes were obtained by blendig ZnO nanoparticles with polysulfone. IR, TG/DTG, XRD and SEM analysis were performed to characterize structure and morphology of ZnO nanoparticles and composite membranes. Contact angle, EWC, porosity and pore structure properties of composite membranes were investigated. Cross-flow filtration studies were performed to investigation of performances of prepared membranes. It was found from the cross section SEM images that ZnO nanoparticles dispersed homogenously up to additive amount of 2% and the membrane skin layer thicknesses increased in the presence of ZnO. Contact angle of pure PSf membranes were reduced from 70\' to 55\' after addition of 4% ZnO. Porositiy of composite membrane contains 1% ZnO was higher about 22% than pure PSf membrane. BSA rejection ratio and PWF of 0.5% ZnO embedded composite membrane became 2.2 and 2.3 times higher than pure PSf membrane. It was determined from flux recovery ratios that ZnO additive increased the fouling resistance of composite membranes. Also, the bacterial killing ability of ZnO is well known and there are many researches related to this in the literature. Therefore, it is expected that prepared composite membranes will show antibacterial effect. | ||
Key Words | ||
membrane; ultrafiltration; water treament; flux; antifouling | ||
Address | ||
Adem Sarihan : Higher Vocational School, Bilecik Seyh Edebali University, 11210, Bilecik, Turkey Erdal Eren : Department of Chemistry, Faculty of Science and Arts, Bilecik Seyh Edebali University, 11210, Bilecik, Turkey | ||