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Membrane Water Treatment
  Volume 6, Number 2, March 2015 , pages 113-126
DOI: https://doi.org/10.12989/mwt.2015.6.2.113
 

Solid-salt pressure-retarded osmosis with exothermic dissolution energy for sustainable electricity production
Wook Choi, Harim Bae, Pravin G. Ingole, Hyung Keun Lee, Sung Jo Kwak, Nam Jo Jeong, Soon-Chul Park, Jong Hak Kim, Jonghwi Lee and Chul Ho Park

 
Abstract
    Salinity gradient power (SGP) systems have strong potential to generate sustainable clean electricity for 24 hours. Here, we introduce a solid-salt pressure-retarded osmosis (PRO) system using crystal salt powders rather than seawater. Solid salts have advantages such as a small storage volume, controllable solubility, high Gibbs dissolution energy, and a single type of water intake, low pretreatment costs. The power densities with 3 M draw solutions were 11 W/m2 with exothermic energy and 8.9 W/m2 without at 35 bar using a HTI FO membrane (water permeability A = 0.375 L m-2 h-1 bar-1). These empirical power densities are ~13% of the theoretical value.
 
Key Words
    salinity gradient power; pressure-retarded osmosis; exothermic; calcium chloride; solid salt
 
Address
(1) Harim Bae, Sung Jo Kwak, Nam Jo Jeong, Soon-Chul Park, Chul Ho Park:
Jeju Global Research Center (JGRC), Korea Institute of Energy Research (KIER), 200 Haemajihaean-ro, Gujwa-eup, Jeju Specific Self-Governing Province 695-971, South Korea;
(2) Wook Choi, Pravin G. Ingole, Hyung Keun Lee:
Greenhouse Gas Research Center, Korea Institute of Energy Research (KIER), 71-2 Jang-dong, Yuseong-gu, Daejeon 305-343, South Korea;
(3) Wook Choi, Jong Hak Kim:
Department of Chemical and Biomolecular Engineering, Yonsei University, 50 Yonsei-Ro, Seondaemun-Gu, Seoul 120-749 South Korea;
(4) Harim Bae, Jonghwi Lee:
Department of Chemical Engineering and Materials Science, Chung-Ang University, 221 Heukseok-Dong, Dongjak-gu, Seoul 156-756, South Korea.
 

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