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Membrane Water Treatment
  Volume 12, Number 2, March 2021 , pages 059-64
DOI: https://doi.org/10.12989/mwt.2021.12.2.059
 

Performance prediction of flat sheet commercial nanofiltration membrane using Donnan-Steric Pore Model
Danial Qadir, Rizwan Nasir, Hilmi Mukhtar and Fahim Uddin

 
Abstract
    The rejection of sodium chloride (NaCl) and calcium chloride (CaCl2) single salt solutions were carried out for commercial nanofiltration NFDK membrane. Results showed that the NFDK membrane had a negative surface charge and had a higher observed rejection of 93.65% for calcium (Ca2+) ion and 78.27% for sodium (Na+) ions. Prediction of rejection for aqueous solutions of both salts was made using Donnan Steric Pore Model based on Extended Nernst-Planck Equation in addition to concentration polarization film theory. A MATLAB program was developed to execute the model calculations. Absolute Average Relative Error (% AARE) was found below 5% for real rejection of the NFDK membrane. This research could be used successfully to assess the membrane characterization parameter using a proposed procedure which can reduce the number of experiments.
 
Key Words
    donnan-steric partitioning model; flat sheet; nanofiltration; Nernst Planck equation; real rejection
 
Address
Danial Qadir and Hilmi Mukhtar: Department of Chemical Engineering, University Teknologi PETRONAS, Sri Iskandar, 32610, Perak, Malaysia

Rizwan Nasir: Department of Chemical Engineering, University of Jeddah, Asfan Road, 23890, Jeddah, Saudi Arabia

Fahim Uddin: Department of Chemical Engineering, NED University of Engineering and Technology, University Road, 75270, Karachi, Pakistan

 

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