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Membrane Water Treatment   Volume 4, Number 1, January 2013, pages 1-9
DOI: https://doi.org/10.12989/mwt.2013.4.1.001
 
Obtaining the zwitterionic form of L-lysine from L-lysine monohydrochloride by electrodialysis
A.E. Aghajanyan, A.O. Tsaturyan, A.A. Hambardzumyan and A.S. Saghyan

 
Abstract     [Buy Article]
    The process of electromembrane transformation of L-lysine monohydrochlorides into their zwitterionic form in four- and two-chamber electrodialysis apparatus was investigated. The process of transformation at various concentrations of lysine monohydrochloride (0.1-0.6 mol.L-1) was studied and it was established that at the optimum density of current optimal concentrations of lysine hydrochloride during electrodyalisis was in the range of 0.2-0.4 mol.L-1. It was determined that the process of total transformation was accomplished when pH of the lysine solution achieved 10. Changes of concentrations of Cl‾ ions and lysine diffused into the neighboring chamber were determined depending on the time. The method developed by us allows adjusting the removal coefficient of Cl‾ ions during transformation to a maximal value, the losses of lysine diffused into the next chamber after its return to the technological cycle being less than 1.0 %. The specific energy consumption during the process of transformation in two- and four-chamber electrodialyzers was 0.19 and 0.205 A.h.kg-1 and the current efficiency was 75.9 and 73.1 %, correspondingly. Study of the process of electromembrane transformation allowed obtaining zwitterionic form of L-lysine from L-lysine monohydrochloride with minimal reagent and energy consumption.
 
Key Words
    electrodialysis; L-lysine monohydrochloride; zwitterion of L-lysine; transformation
 
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